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Substrate catalyzes on-surface reactions

Speaker: Dr. GAO Hongying
Physikalisches Institut, Westfälische Wilhelms-Universität, Wilhelm-Klemm-Straße 10, 48149 Münster (Germany)
Time: 2017-10-30 10:00
Place: ROOM 9004, Hefei National Laboratory Building


  In the on-surface chemistry area, an important topic is how the surface serves for reactions. To reveal this aspect, Glaser coupling, decarboxylation, amine-coordination, Ullman coupling, domino-reaction, C-C or C-H coupling, carbene-reaction and sigma bond metathesis were systematically investigated at various metal surfaces, which prove that the surface acts not only as a supporting surface but also a catalyst. Further, various organometallic intermediate states were observed in experiments, that help to understand how the surface atoms take part in the reactions.

Organizer: Hefei National Laboratory for Physical Sciences at the Microscale

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