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Waterborne polyacrylates with thermally activated delayed fluorescence and two-state phosphorescence
Materials Chemistry Frontiers 2(3):559-565 Mar 2018

Wang, Tao; Tang, Zhen; Xu, Dong; Sun, Wei; Deng, Yipeng; Wang, Qidong; Zhang, Xingyuan; Su, Peifeng; Zhang, Guoqing

Purely organic luminescent materials are extensively used in bioimaging, sensing and organic light-emitting diodes (OLEDs). Anthraquinone (AQ) derivatives with N- and O-substitution are incorporated into waterborne polyacrylates as single-component polymers with both thermally activated delayed fluorescence (TADF) and two-state phosphorescence. Essential structural and optical properties are characterized for these waterborne polyacrylates. With increasing dye loadings, a convergence between singlet and triplet states due to excitonic splittings is observed.

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