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Low-cost CuNi@MIL-101 as an excellent catalyst toward cascade reaction: integration of ammonia borane dehydrogenation with nitroarene hydrogenation
2017-12-05
Chemical Communications 53(91):12361-12364 Nov 2017

Zhou, Ying-Hua; Yang, Qihao; Chena, Yu-Zhen; Jiang, Hai-Long

Abstract:
Bimetallic CuNi nanoparticles (NPs) with low cost were rationally confined inside MIL-101 to give CuNi@MIL-101, which exhibits high efficiency and excellent recyclability toward the hydrogenation of nitroarenes under mild conditions on coupling with ammonia borane dehydrogenation. This is the first report on MOF-stabilized base metal NPs for cascade reactions.

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