Carbon materials (CMs) exhibit great application potentials in diverse fields due to their high electric conductivity, good chemical stability, and unique microstructure. Traditionally, CMs were prepared by the carbonization of low-vapor-pressure natural products or synthetic polymers. But they suffer from some distinct disadvantages, such as difficulty in tailoring the microstructures and chemical compositions of the obtained products, or complicated and slow polymerization processes. Up to now, it is still a significant challenge to develop a facile, low-cost, and highly controllable method for preparing CM with desired constituents and structures in a large scale.
Recently, a research team led by Prof. YU Shuhong and Prof. LIANG Haiwei from the University of Science and Technology of China (USTC) proposes a simple, effective, and versatile method to prepare a series of functional CMs from small organic molecules (SOMs) by a transition metal assisted carbonization process. This work was published on Science Advances entitled as “Transition metal-assisted carbonization of small organic molecules toward functional carbon materials” on July 27th (Science Advances 2018, 4, eaat0788).
Preparation of CMs.(A) Schematic illustration of the preparation process of CMs.(B) Structures of the investigated SOMs for the CM preparation. (Image by YU Shuhong)
Small organic molecules (SOMs) as precursors for preparing CMs have some distinct advantages, such as common availability, relatively low cost, and diverse element species with various contents. Previous efforts on the transformation of SOMs into CMs almost relied on harsh synthesis conditions, e.g. pyrolysis in sealed reactors, chemical vapor deposition, or salt-melt-based ionothermal carbonization, due to the high volatility of SOMs at evaluated temperatures. To address this, the research group led by Prof. YU Shuhong and Prof. LIANG Haiwei develops a method of transition metal assisted carbonization of SOMs. The transition metals can catalyze the preferential formation of thermally stable intermediate polymeric structures and thus avoid the direct sublimation of SOMs during the heating process, which guarantees the successful preparation of CMs with high carbon yield. Researchers have found that totally fifteen SOMs and nine TMSs can be employed as carbon precursors and catalysts respectively for preparing CMs. Besides, two hard templates can used in the method to enhance the porosity of obtained CMS. All of research results indicate that the method is a simple, effective, and versatile method to prepare CMs.
The prepared CM exhibited three different prominent microstructures (including bamboo-like multi-walled carbon nanotube, micrometer-sized nanosheets and irregular particles) that were highly dependent on the molecular structures of SOMs. Besides, the CMs possessed high specific surface areas, large pore volumes, abundant heteroatoms as well as highly graphitic structures. As a result, the CM showed great application potentials for heterogeneous catalysis, e.g. selective oxidization of ethylbenzene and hydrogenation of nitrobenzene, and electrocatalysis, e.g. hydrogen evolution reaction and oxygen reduction reaction. This work opens a new window for the synthesis of CMs with desired constituents and structures.
This work was supported by National Natural Science Foundation of China, Foundation for Innovative Research Groups of the National Natural Science Foundation of China, Key Research Program of Frontier Sciences, National Basic Research Program of China, Users with Excellence and Scientific Research Grant of Hefei Science Center of CAS, “the Recruitment Program of Global Experts”, National Postdoctoral Program for Innovative Talents, China Postdoctoral Science Foundation, Fundamental Research Funds for the Central Universities.
(Edited by HU Dongyin, USTC News Center)